Dept. of Biochemistry & Organic Chemistry

Adolf Gogoll

Research Interests:	Organometallic Chemistry
	Molecular tools
	Photoswitchable peptidomimetics

Organometallic chemistry: Mechanisms, structures, dynamic phenomena

Structural and mechanistic aspects in organic, organometallic, and medicinal chemistry.

Reactions and syntheses

Microwave-Assisted Raney Nickel Reduction of Bispidinone Thioketals to N,N’-Dialkylbispidines. L. Toom, H. Grennberg, A. Gogoll, Synthesis 2006, 2064.

Bispidine synthesis

Rapid Microwave-Promoted Sonogashira Coupling Reactions on Solid Phase. M. Erdélyi and A. Gogoll, J. Org. Chem. 2003, 68, 6431.

Rapid Homogeneous-Phase Sonogashira Coupling Reactions Using Controlled Microwave Heating. M. Erdélyi and A. Gogoll, J. Org. Chem. 2001, 66, 4165.

Sonogashira coupling

Structure and dynamics

Ligand-Induced Formation of an Adamantanoid Hexanuclear (π-Allyl)PdII(μ3-Hydroxo) Cluster Stacked as Hydrogen-Bonded Double Strands. A. Gogoll, L. Toom, and H. Grennberg, Angew. Chem. Int. Ed. 2005 , 44, 4729.

Pd oxocluster

N,N'-Diphenylbispidinone Derivatives as a New Type of Chelating Nitrogen
Ligand for Stereochemical Analysis of (π-Allyl)palladium Complexes: Complexation Studies and X-Ray Structure of (3,7-diphenyl-1,5-dimethylbispidinone)-[1,3-η3-propenyl-palladium] trifluoro-methane sulfonate. A. Gogoll, H. Grennberg, and A. Axén, Organometallics 1997, 16, 1167.

Pd-piallyl bpd

Mechanism of Apparent π-Allyl Rotation in (π-Allyl)Palladium Complexes with Bidentate Nitrogen Ligands. A. Gogoll, J. Örnebro, H. Grennberg, and J.E. Bäckvall, J. Am. Chem. Soc. 1994 , 116 , 3631.

Apparent pi-allyl rotation